Publié

or physical chemistry

A NADPH substitute for selective photo-initiation of reductive bioprocesses via two-photon induced electron transfer.

Publié le - Chemical Communications

Auteurs : Anne-Claire Robin, Saïd Gmouh, Olivier Mongin, Viatcheslav Jouikov, Martinus Werts, Clément Gautier, Anny Slama-Schwok, Mireille Blanchard Desce

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A NADPH substitute where the nicotinamide moiety is replaced by a chromophoric unit having much larger two-photon absorption cross-section and able to transfer electrons to flavins only upon excitation is described as an effective two-photon nanotrigger for selective photo-activation of electron transfer in bioreductive processes.